Attempting to restore SQL Server 2005 database to a SQL Server 2008 R2 instance gives reason: 15105 error

I have a SQL Server 2005 database I am attempting to restore a SQL Server 2008 R2 SP2 machine using this statement:

RESTORE DATABASE [Db] 
FROM  DISK = N'C:\temp\sql\DB.bak' WITH  FILE = 1,  
MOVE N'DB' TO N'C:\Program Files\Microsoft SQL Server\MSSQL.1\MSSQL\NewDB.mdf',  
MOVE N'DB_Log' TO N'C:\Program Files\Microsoft SQL Server\MSSQL.1\MSSQL\NewDB.ldf',  
REPLACE,  STATS = 10
GO

But It keeps giving this error.


Msg 3634, Level 16, State 1, Line 1

The operating system returned the error '5(failed to retrieve text for this error. Reason: 15105)' while attempting 'RestoreContainer::ValidateTargetForCreation' on 'C:\Program Files\Microsoft SQL Server\MSSQL.1\MSSQL\NewDB.mdf'.

Msg 3156, Level 16, State 5, Line 1

File 'Db' cannot be restored to 'C:\Program Files\Microsoft SQL Server\MSSQL.1\MSSQL\NewDB.mdf'. Use WITH MOVE to identify a valid location for the file.

Msg 3634, Level 16, State 1, Line 1

The operating system returned the error '5(failed to retrieve text for this error. Reason: 15105)' while attempting 'RestoreContainer::ValidateTargetForCreation' on 'C:\Program Files\Microsoft SQL Server\MSSQL.1\MSSQL\NewDB.ldf'.

Msg 3156, Level 16, State 5, Line 1

File 'Db_Log' cannot be restored to 'C:\Program Files\Microsoft SQL Server\MSSQL.1\MSSQL\NewDB.ldf'. Use WITH MOVE to identify a valid location for the file.

Msg 3119, Level 16, State 1, Line 1

Problems were identified while planning for the RESTORE statement. Previous messages provide details.

Msg 3013, Level 16, State 1, Line 1

RESTORE DATABASE is terminating abnormally.

I am logged into SQL Server as SA. I have Admin permissions on the system.

I have also tried to remove the restore location to another path (that has full permission) with the same error.

"MSSQL.1" is not the directory for a SQL Server 2008 R2 instance.

You should verify the directory you are trying to place the database in. The default data path for a normal installation is: "C:\Program Files\Microsoft SQL Server\MSSQL10_50.MSSQLServer\MSSQL\Data".

Edit

If this is indeed the path of the databases for your SQL Server 2008 R2 instance then you can verify this by running the following query:

SELECT name, physical_name
FROM sys.master_files
WHERE database_id = 1

You should get results similar to this, highlighted the path for my instance:

You can also verify this path through the restore prompt in SSMS, clicking on the "files":

However also noting that the error message operating system returned the error '5, the 5 normally indicates permissions issue with the service account running the database engine. If the full message was provided you would see something like


The operating system returned the error '5(Access is denied)' while attempting 'RestoreContainer::ValidateTargetForCreation'

StackExchange Database Administrators Q#55218, answer score: 4